中性载体阳离子电极膜电化学的计算机数字模拟

Digital Simulation of Neutral Carrier Cation Selective Electrode Membrane Electrochemical Properties

对中性载体阳离子电极膜３种可能的传输模式进行了数字模拟，研究了淌度、浓度、配合物稳定常数以及阴离子亲脂性对电极电位响应的影响．模拟结果对于廓清这类电极响应机理，解释有关实验现象及指导新电极设计提供了有用的信息。

Digital simulation techniques are applied to investigate the electrochemical properties of neutral carrier cation selective electrode membranes with a particular attention bening paid to three possible transport mechnisms. The effects of mobilities, concentrations,complex formation constants and hydrophilic anions on potention response are studied.The simulation results provide useful information for exploring the response mechanism of this type of electroded,explaining some experimental phenomena and designing new neutral carrier electrodes.