Au（Ⅲ）的含硫希夫碱配合物的合成和性质

Syntheses and Characterization of Au(Ⅲ) Complex with Schiff Base Containing Sulfer

合成了Ａｕ（Ⅲ）与苯乙酰缩氨基硫脲形成的１∶２型配合物。经元素分析，确定其分子式为．并用红外谱、紫外吸收光谱，核磁共振谱对该配合物进行了结构表征；用差示扫描量热法计算了其热分解反应的△Ｈ，活化能，反应级数；研究了其摩尔电导与溶解性能。

A complex of gold with acetophenon thiosemicarbazone was prep-ared.The elementary analyses revealed that the formula of the complex wasThe structure of the complex was characterized by IR, UV,H'NMR,and themolecular conductance.The enthalpy,activation energy,and the reaction orderfor the decomposition of the complex were calculated by the method of DSC.The solubility of the complex was studied.