硝酸铀酰与TDD配合物的合成及性质研究

SYNTHESIS AND CHARACTEIZATION OF THE COMPLEX OF URANYL NITRATE WITH N,N,N’,N’-TETRAPHENYL-3,6-DIOXAOCTANEDIAMIDE

在氯仿－甲醇混合溶剂中，合成了Ｎ，Ｎ，Ｎ’Ｎ’－四苯基－３，６－二氧杂辛二酰胺（ＴＤＤ）与硝酸铀酰的固体配合物，其分子式为［ＵＯ＿２（ＮＯ＿３）＿２（ＴＤＤ）］。通过元素分析、红外光谱、热分析、￣１ＨＮＭＲ谱和摩尔电导率对该配合物进行了表征。

The solid complex of uranyl nitrate with N,N,N’,N’-tetraphenyl-3,6-dioxaoctanediamide(TDD)is prepared in a chloroform-ethanol solution. The new complex with the formula[UO_2(NO_3)_2(TDD)]is characterized by element analysis,IR spectra ,TG-DTA technique,￣1HNMR spectra and molar eletric conductivitv.