摘要
以二苯腈二氯化钯为催化剂,在固液相转移条件下,芳基磺酰氯能与N,N-双烷基取代丙烯酰胺发生偶联反应,生成柏应的E式不饱和酰胺。
The coupling reaction of arenesulphonyl chlorides with N, N-dialkyl substituted acry-lamides in the presence of a catalytic amount of bis(benzonitrile) dichloropolladium can take place un-der solid-liquid phase-transfer conditions and give conespounding (E)-α ,β-unsaturated amides.
出处
《合成化学》
CAS
CSCD
1994年第2期135-139,共5页
Chinese Journal of Synthetic Chemistry
基金
浙江省自然科学基金资助项目
关键词
钯
催化
芳基磺酰氯
丙烯酰胺
偶联
Palladium catalysis, Phase transfer catalysis, Unsaturated amides, Stereoselectivesynthesis.