摘要
用高效RSP-Cu_3Si合金催化剂,气化的氯苯PhCl与氯甲烷在400℃同时经过催化剂RSP-Cu_Si可制得重要硅烷化试剂(CH_3)_mPh_nSiCl_(4-m-n)讨论了反应的最佳条件及速度。
The important silylation agents,(CH_3)_m Ph_n SiCl _(4-m-n)(CH_3PhSiCl_2 phenylmethyldichlorosilane,(CH_3)2-PhSiCl phenyldimetbylchlorosilane,CH_3Ph_2SiCl diphenyldimetbylchlorosilane,can be synthesized by Rochow process with efficient alloy RAP-Cu_3Si catalyst when gasified PhCl and CH_3Cl pass over the catalyst simultaneously at 400℃.The optimum conditions and the rates of this reaction are discussed.
出处
《化学试剂》
CAS
CSCD
北大核心
1994年第2期83-84,109,共3页
Chemical Reagents
关键词
硅烷化试剂
苯氯硅烷
合成
silylation agents,silane (CH_3)_m(C_6H_5)n-SiCl4-m-n),phenylmethylchlorosilane,RSP-Cu_3Si,synthesis