摘要
根据简正坐标分析的部分结果对标题配合物的实测红外和拉曼光谱进行了标识.计论了C=C,N-S伸缩振动频率随配合物氧化态变化而红移或兰移的规律及意义.
Abstract Based on normal vibration analysis, the IR and Raman spectra of the title complexes areidentified. The red-shift or violet-shift variahons of C = C and M-S stretching frequencies withthe oxidation states of coordination anions [M(dmit)_2] ̄(δ-)are discussed.