固相配位化学反应研究 LVⅢ.2,2′-对苯二甲硫基二乙酸与醋酸铜在低热温度下的固相化学反应

Studies on the Solid State Reactions of Coordination Compounds LVⅢ. The Solid-Solid State Reaction of 2,2'-(p-Phenylenedimethylenethio)diacetic Acid with Copper Acetate Monohydrate at Low Heating Temperature

本文研究2,2’-对苯二甲硫基二乙酸与一水醋酸铜在低热温度下发生的固-固相配位化学反应.用XRD,IR,ESR和元素分析等手段表征反应在50℃进行8h后的固相产物.用电导法研究等温固相反应,探讨可能的动力学机理,并计算了固相反应的动力学参数.

In this paper, the solid-solid state reaction of 2,2'-(p-phenylenedimethylenethio) diacetic acid with copper acetate monohydrate was studied. XED, IR, ESR and elemental analysis were used to characterize the solid product. The kinetics of the isothermal solid state reaction was investigated by using the electrical conductivity measurement. Possible mechanism was discussed, and kinetic parameters were calculated.