摘要
本文研究了10%钯/碳存在时,以甲酸铵为氢给予体的多氯联苯(PCBs)脱氯的催化转移氢化方法.在中性介质、低温、常压下.PCBs脱氯效率达98—100%.该方法已用于电容器中PCBs的脱氯.
The catalytic transfer hydrogenolytic procedure, in the presence of 10% palladium on carbon, using ammonium formate as hydrogen donor, for the dechlorination of polychlorinated biphenyls (PCBs) was studied. 94 - 100% precem efficiencies of the dechJorintion was achieved in neutral media under low temperature (60℃) and ambient pressure. The procedure has been applied to dechlorination of PCBs in capacitor.
出处
《环境化学》
CAS
CSCD
北大核心
1994年第4期328-331,共4页
Environmental Chemistry
关键词
催化转移氢化
多氯联苯
脱氯
catalytic transfer hydrogenolysis, polychlorinated biphenyls, dechlorination.