摘要
本文从统计力学理论出发，采用定标粒子理论，对气体在甲醇中的溶解度进行了计算。通过采用作者提出的计算溶质和溶剂的Ｌｅｎｎａｒｄ－Ｊｏｎｅｓ能量参数的公式，使得计算结果与文献值及原设计值符合较好。因而可以在流程模拟系统及工程设计计算中采用这种简捷而又准确的方法。
From statistical mechanics,the solubilities of gases in methanol are calculated using the Scaled-Partical Theory.The result obtained with the formula presented by the authors for calculating Lennard-Jones energy parameter of solutes and solvent meets with the value of literature and original design very well.The simple and accurate method can be used for the process simulation and engineering design calculation.
出处
《计算机与应用化学》
CAS
CSCD
1994年第1期44-51,共8页
Computers and Applied Chemistry
关键词
甲醇洗
溶解度
合成氨
脱碳
脱硫
RECTISIL process,Solubility,Scaled-partical theory, Statistical mechanics, Herry's constant
