摘要
报道11中含R_2NCS_2配体的过渡金属配合物的~1HNMR研究结果。对其顺磁性化合物的磁性和电子结构进行了讨论;并探讨了抗磁性化合物的分子结构和NMR关系。
Eleven transition metal complexes containing ligands R_2NCS_2 were studied by ̄1H NMR spectra.The magnetic characteristics and electronic structure were discussed for paramagnetic compounds.While the corelation between molecular structure and ̄1H NMR was discussed briefly for diamagnetic compounds.
关键词
RNCS2
过渡金属
络合物
NMR
dialkyldithiocarbamate,transition metal complexes, ̄1H NMR.