摘要
本文首次建立了不对称合成反应中热力学函数之间的相互关系,阐明了不对称合成手性产率随构型熵和温度变化的规律,在不对称合成中具有重要的理论和实际意义.
The relationship among the thermodynamic functions in asymmetric synthesis was first established.Thelaw of the ration of steric isomerides changing with temperature and entropy was explained satisfactorily.Thisis significant for asymmetrical synthetic chemistry.
出处
《科技通报》
1994年第5期281-283,共3页
Bulletin of Science and Technology
关键词
不对称合成
热力学
有机合成
asymmetric synthesis
steric isomeride
thermodynamic
configuration entropy