摘要
本文介绍了以菜油中的芥酸为原料合成环十三酮、环十三内酯、环十五酮、环十五内酯和环十六酮的新路线,并对某些关键反应进行了一些改进和新的探讨。
Several macrocyclic musk compounds:cyclotri decanone,cyclotride-canolide,cyclopentadecanone, cyclopendecanolide,and cycloheptadecanone are synthesizedstarting from erucic acid seperated from rapeseed oil.PTC is used in the oxidation of erucic acid to brassylic acid by KMnO4,and raises the yield greatly.
出处
《南昌大学学报(工科版)》
CAS
1994年第2期77-81,共5页
Journal of Nanchang University(Engineering & Technology)
关键词
芥酸
环十三酮
环十三内酯
环十五酮
菜油
麝香
Erucic acid, Synthesis,Cyclotyidecanone,Cyclotridecanolide, Cy-clopentadecanone,Cyclopentadecanolide,Cycloheptadecanone