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顺反异构化过程及其机理 被引量：7

Advances in process and mechanism of cis-trans isomerism
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摘要 总结了分子中存在的顺反异构化过程及其机理,包括光致异构化、热致异构化和催化异构化。 Advances of the cis-trans isomerism in a molecule are summarized in this paper.The contents include different cis-trans isomerization process (including photoisomerization, thermal iso-merization and catalytic isomerization), mechanism and the problems to be solved.
作者 李锋 王敏
机构地区 中国农业大学理学院
出处 《化学试剂》 CAS CSCD 北大核心 2005年第1期21-23,26,共4页 Chemical Reagents
关键词 顺反异构 构效 机理 cis-trans isomerism structure-activity relationship mechanism
分类号 O643 [理学—物理化学]
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参考文献23

  • 1Crombie K. Cis-trans isomerism was formedy called gemetricar isomerism[J]. Q. Rev. Chem. Soc., 1952, (6): 101-140.
  • 2Padwa A,Albrecht F. Concentration effects in the photochemical syn-anti isomerization of an oxime ether[J]. J. Org.Chem., 1974,39(16) :2361-2366.
  • 3游长江,谢蓉,杨国强,李嫕.烯烃光敏顺反异构化反应[J].感光科学与光化学,2003,21(2):147-155. 被引量：3
  • 4Chen R L, Liu R S. New hindered isomers of 3-dehydroretinal (Vitamin A2)[J]. Tetrahedron, 1996,52(23):7809-7816.
  • 5Pfoertner K H.Novd photosensifzers for the E/Z-isomerization of trienes. Part 1. Syntheses and application [J]. J.Chem. Soc. , Perkin Trans. , 1991,2:523-526.
  • 6Willam M H, Pill-Soon Song. CRC Handbook d Organic Photochemistxy and Photobiology[M]. Florida: CRC Press Inc., 1995.3-16.
  • 7Hammond G S, Saltiel J, Lamola A A, et al. Mechanisms of photochemical reactions solution. ⅩⅫ. Photochemical cistram isomerization[J]. J. Am. Otem. Soc., 1964,86(16):3197-3217.
  • 8Bent D V,Schuhe-Frohlinde D.l.a.ser flash photolysis of subsfituted stilbenes in solution[J]. J. Phys. Chem., 1974,78:446-450.
  • 9Waldeck D H. Photoisomerization dynamics of stilbenes[J]. Chem. Rev. , 1991,91:415-436.
  • 10Salfid J. Perdeuteriostilbene. The role of phantom states in the cis-trans photoisomerization of stilbenes [J]. J. Am. Chem. Soc., 1967,89(4) : 1036-1037.

二级参考文献45

  • 1[1]Wald G.Molecular basis of visual excitation[J].Science,1968,162:232-239
  • 2[2]Chen R L,Liu R S H.Hindered isomers of 3-dehydroretinal(Vitamin A2)[J].Tetrahedron,1996,52:7809-7816.
  • 3[3]Pfoertner K H.Novel photosensitizers for the E/Z-isomerization of trienes.Part 1.Syntheses and application[J].J.Chem.Soc.Perkin Trans.2,1991,523-526.
  • 4[4]William M H,Pill-Soon Song.CRC Handbook of Organic Photochemistry and Photobiology[M].Florida:CRC Press Inc.,1995,3-16.
  • 5[5]Hammond G S,Saltiel J,Lamola A A,et al.Mechanisms of photochemical reactions solution.XXII.Photochemical cis-transisomerization[J].J.Am.Chem. Soc.,1964,86:3197-3217.
  • 6[6]Bent D V,Schulte-Frohlinde D.Laser flash photolysis of substituted stilbenes in solution[J].J.Phys.Chem.,1974,78:446-450.
  • 7[7]Bent D V,Schulte-Frohlinde D.Evidence for the triplet route in the photochemical trans-cis isomerization of nitrostilbenes in solution[J].J.Phys.Chem.,1974,78:451-454.
  • 8[8]Grner H,Schulte-Frohlinde D.Upper excited triplet state mechanism in the trans-cis isomerization of 4-bromostilbene[J].J.Am.Chem.Soc.,1979,101:4388-4390.
  • 9[9]Grner H,Schulte-Frohlinde D.Observation of the triplet state of stilbene in fluid solution.Determination of the equilibrium constant(3t*=1p*)and of the rate constant for intersystem crossing(3p*→1p*)[J].J.Phys.Chem.,1981,85:1835-1841.
  • 10[10]Waldeck D H.Photoisomerization dynamics of stilbenes[J].Chem.Rev.,1991,91:415-436.

共引文献11

同被引文献74

引证文献7

二级引证文献16

化学试剂
2005年 第1期

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