2-[2-(5-甲基-1,3,4-噻二唑)偶氮]-5-二甲基氨基苯酚及其镍螯合物的合成与性质研究

Synthesis and properties of 2-[2-(5-methyl-1,3,4-thiadiazole)azo] -5-N,N-Di-methylaminophenol and its nickel chelate

以 2-氨基-5-甲基-1, 3, 4-噻二唑, 3-N,N-二甲基氨基苯酚,四水合乙酸镍为主要原料合成了未见文献报导的 2-[2-(5-甲基-1, 3, 4-噻二唑)偶氮] -5-二甲基氨基苯酚及其镍螯合物。并采用元素分析、质谱、核磁、ICP发射光谱及红外光谱等对目标产物进行了表征,同时研究了它们的电子吸收光谱性质和热学性质。

methyl-1,3,4-thiadiazole)azo]-5-N,N-Di-methyl-aminophenol and its nickel dye are synthesized with 2-amino-5-methyl-1,3,4-thiadiazole, 3-N,N-Di-methyl-aminophenol and nickel acetate tetrahydrate as raw material.The product were confirmed by element analysis,mass spectrum,~1HNMR spectra, infrared spectrum and ICP emission spetroscopy,and their electron absorption spectrum and the thermal property are studied.