含氮茂铁异核金属配合物的合成和性质研究

SYNTHESIS AND PROPERTIES STUDY OF THE CONTAIN NITROGEN FERROCENE HETERONUCLEAR ORGANO-METALLIC COORDINATION COMPOUNDS

Ｐｄ（Ⅱ）、Ｐｔ（Ⅱ）ＤＭＡＦ配合物已合成，并已定结构［１］．本文采用ＭＸ２（Ｍ＝Ｎｉ（Ⅱ），Ｃｏ（Ⅱ），Ｚｎ（Ⅱ），Ｃｕ（Ⅱ）；Ｘ＝Ｃｌ，Ｂｒ，Ⅰ）在ＣＨ２Ｃｌ２中和ＤＭＡＦ作用合成［ＭＸ２·２ＤＭＡＦ］型配合物．由ＮｉＣｌ２·２ＤＭＡＦ·Ｃ７Ｈ８晶胞参数推知属于对称链状四配位结构．ＩＲ谱表明，该化合物化学式为ＭＸ２·２ＤＭＡＦ．ＣＶ表明配合物中Ｍ（Ⅱ）和Ｆｅ（Ⅱ）存在．由于金属离子互相影响，Ｅｐ／２随Ｍ（Ⅱ）性质呈规律性变化．

The compounds of [MX2. 2DMAF] can be made in the neutral medium, such as CH2Cl2etc; (M = Ni(Ⅱ), Co(Ⅱ), Cu(Ⅱ), Zn(Ⅱ); X= Cl, Br,(Ⅰ).[NiCl2. 2DMAF]. C7H8 can beCrystallizing in toluene, the metal atom M(Ⅱ) is on the crystallographic symmetry ccnter. TheirIR spectra were studied. The effect between M(Ⅱ) and Fe(Ⅱ) cause the change of Ep valuerigularly according to the characters of M(Ⅱ).