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聚乙二醇支撑的二醋酸碘苯试剂参与1,3,4-噁二唑化合物的合成

Poly (Ethylene Glycol) Supported (Diacetoxy) Iodobenzene in the Synthesis of 1,3,4-Oxadiazoline Derivatives
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摘要 聚乙二醇支撑的二醋酸碘苯作为可溶性聚合物试剂在常温下将醛的N-酰基腙氧化成环,以中等到良好的产率生成了1,3,4-二唑衍生物,该试剂在此反应中显示出较好的反应活性,反应条件温和,并且可循环使用,对环境友好. Poly (ethylene glycol) by supported (diacetoxy) iodobenzene as a soluble polymer reagent can smoothly oxidze aldehyde N-acylhydrazones to 1,3,4-oxadiazone derivatives at room temperature in moderate to good yields. This soluble polymer supported by hypervalent iodine agent exhibites enough reactivity for the oxidative cyclization of aldehyde N-acylhydrazones under mild conditions.Moreover, it can be regenerated and reused as environmentally benign reagent.
作者 黄斌 桑晓燕 张奖平 汪秋英 刘晓玲 林淑英 盛寿日
机构地区 江西师范大学化学化工学院
出处 《江西师范大学学报（自然科学版）》 CAS 北大核心 2005年第1期64-67,共4页 Journal of Jiangxi Normal University(Natural Science Edition)
基金 江西省自然科学基金(No.0420017)资助项目.
关键词 醋酸 合成 聚乙二醇 环境友好 反应条件 产率 试剂 噁二唑 可溶性聚合物 酰基 soluble polymer reagent polyethylene glycol (diacetoxy)iodobenzene aldehyde N-acylhydrazone 1,3,4-oxadiazone oxidative cyclization
分类号 N941.5 [自然科学总论—系统科学] O621 [理学—有机化学]
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参考文献15

  • 1Behr L C. Application of oxadiazoline derivatives[ J]. Chem Heterocycl Compd, 1962, 17 (1): 263.
  • 2Baltazzi E, Wysocki A J. Preparation of 1,3,4- oxadiazoline derivatives[ J]. Chem Ind (London), 1963:1 080.
  • 3Chiba T, Mitsuhiro O. Electrooxidative cyclization of N- acylhydrazones of aldehydes and ketones to DELTA 3 - 1,3,4- oxadiazolines and 1,3,4-oxadiazoles[J].J Org Chem, 1992, 57 (5): 1 375-1 379.
  • 4Gladstone W A F, Ayiward J B,Norman R O C. Reactions of lead tetraacetate ⅩⅧ: Oxidation of aldehyde hydeazones: New methods for the generation of nitrilimines[J] .J Chem Soc (C), 1969:2 587- 2 589.
  • 5Stang P J,Zhdankin V V. Organic polyvalent iodine compounds[J].Chem Rev, 1996,96 (3):1 123- 1 178.
  • 6Moriarty R M, Vaid R K. Carbon-carbon bond formation via hypervalent iodine oxidations[ J]. Synthesis, 1990, (6):431- 447.
  • 7Chen D W, Chen Z C. Hypervalent iodine in synthesis ⅪⅩ: Oxidation of aldehyde hydrazones with phenyliodine diacetate: A new method for the generation of nitrilimines[J]. Synth Commun, 1995, 25 (6):1 617- 1 626.
  • 8Chen D W, Chen Z C. Hypervalent iodine in synthesis ⅩⅥ: Reagenration of carbonyl compounds from semicarbazones by phenyliodine (Ⅲ) diacetate (PID)[J].Synthesis, 1994, (8): 773-774.
  • 9Yang R Y, Dai L X. Hypervalent iodine oxidation of N- acylhydrazones and n - phenylsemicarbazone: An efficient method for the synthesis of derivatives of 1, 3, 4- oxadiazoles and △3 - 1, 3, 4 - oxadiazolines[J] .J Org Chem, 1993, 58(12): 3 381 - 3 383.
  • 10Huang X,Zhu Q. The application of cross- linked poly[styrene (iodosodiacetate) ] to the synthesis of 1, 3, 4- oxadiazoles[J] .J Chem Res(S),2000, (3): 300- 301.

二级参考文献36

  • 1[1]Pillai V.N.R.,Mutter M..Acc.Chem.Res.[J],1981,14:122.
  • 2[2]Wentworth P.,Janda K.D..Chem.Commun[J],1999:1917.
  • 3[3]Sauvagnat B.,Lamaty F.,Lazaro R.,Martinez J..Tetrahedron Lett.[J],1998,39:821.
  • 4[4]Dauvagnat B.,Lamaty F.,Lazaro R.,Martinez J..Tetrahedron Lett.[J],2000,41:6371.
  • 5[5]Blettner C.G.,Konig W.A.,Stenzel W.,Schotten T..Synlett.[J],1998:295.
  • 6[6]Blettner C.G.,Konig W.A.,Stenzel W.,Schotten T..J.Org.Chem.[J],1999,64:3885.
  • 7[7]Reggelin M.,Brenig V.,Zur C..Org.Lett.[J],2000,2:531.
  • 8[8]Cheng S.,Comer D.D.,Myers P.L.,Saunders J..Tetrahedron Lett.[J],1999,40:8975.
  • 9[9]Chen Z.,Yang G.,Zhang Z.,Wang D..Synthesis[J],2001:2235.
  • 10[10]Moore M.,Norris P..Tetrahedron lett.[J],1998,39:7027.

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江西师范大学学报（自然科学版）
2005年 第1期

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