摘要
报导了用分光光度法测定双核钴(Ⅱ)卟啉与有机碱反应的平衡常数及组成比,并研究了双核钴卟啉与CO的轴向配位作用,结果表明,双核钴卟啉与CO的结合是可逆的.用红外差谱法测得CO的伸缩振动频率是1959cm-1.
Equilibrium constants and component ratio of reaction of dicobalt porphyrin complexes with organic bases were measured by spectrophotometric method. The adduct of dicohalt porphyrin with CO were studied. Experimental resultS show that the adduct reaction is reversible. The CO stretching vibration frequency 1959 cm1 was obtained by using IR differential spectrum method.
出处
《武汉大学学报(自然科学版)》
CSCD
1994年第3期79-82,共4页
Journal of Wuhan University(Natural Science Edition)
基金
国家自然科学基金
关键词
卟啉
轴向配位
钴
络合物
dicoblt(Ⅱ ) porphyrin
axial coordination
spectrophotometry