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Syntheses and Application of New Room Temperature Ionic Liquids Based on Hexaalkylguanidinium Salts 被引量:3

Syntheses and Application of New Room Temperature Ionic Liquids Based on Hexaalkylguanidinium Salts
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摘要 A new series of guanidinium cation-based room temperature ionic liquids(RTILS) was prepared by treating tetraalkylguanidine with an alkylating agent in the presence of an alkaline reagent and a phase transfer catalyst(PTC). Good results were obtained when GPF_6 was used as the reaction medium for the selective oxidation of benzyl alcohol with sodium hypochlorite as the oxidant. A new series of guanidinium cation-based room temperature ionic liquids(RTILS) was prepared by treating tetraalkylguanidine with an alkylating agent in the presence of an alkaline reagent and a phase transfer catalyst(PTC). Good results were obtained when GPF_6 was used as the reaction medium for the selective oxidation of benzyl alcohol with sodium hypochlorite as the oxidant.
机构地区 CollegeofChemistry
出处 《Chemical Research in Chinese Universities》 SCIE CAS CSCD 2005年第2期158-162,共5页 高等学校化学研究(英文版)
关键词 Ionic Liquid Hexaalkylguanidinium OXIDATION Benzyl alcohol Ionic Liquid, Hexaalkylguanidinium, Oxidation, Benzyl alcohol
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