摘要
采用扫描电镜与波谱学技术(EPR谱和激光拉曼谱)相互配合的方法,获得了小秦岭地区的含金黄铁矿中存在有晶格金的佐证.在扫描电镜下,黄铁矿中Au的x射线面分布图呈均匀分散的细小斑点;Au+的EPR超精细结构谱线g因子为2.05±0.15;An+-伸缩振动的拉曼位移,经计算和实验测定Δv为370~390cm-1.
So far,lattice gold has been discovered continuously in pyrite in many gold deposits,but it has never beenfound in the Xiao Qinling auriferous mineral zone. Thus. the author studies the gold-bearing pyrite whichwas generated in the Xiao Qinling auriferous mineral zone by using scanning electron microscope and wavelength dispersive spectromater and gets the evidence for lattice gold in gold-bearing pyrite. The X-ray surfacedistribuing graph shows the An beared in pyrite is even and disperse small speckes. By using the EPR spectrum analysis, a fine texture spectral line with g(factor) =2. 05±0. 15 wes obtained. Raman line shift (Δγ) of flexible vibration of An+ - is 370~390cm-1. that is experimened and calculated by the author.