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硫酸羟胺与水合肼对B-Z反应的影响

The Effects of Hydroxylamine Sulfate and Hydrated Hydrazine on the B-Z Reaction
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摘要 In this paper the effects of hydroxylamine sulfate and hydrated hydrazine on the B-Z reaction are studied. Hydroxylamine sulfate and hydrated hydrazine can react with BrO to produce Br-. They show some analogies with vitamin C in their effects on B-Z reaction, that is, they sbolarly lengthen the induction period and oscillating period,and shorten the life-span of this oscillating reaction.From this reason the conjecture of reaction mechanism that is proposed by Zhao Xuezhuang et al can be confirmed. In this paper the effects of hydroxylamine sulfate and hydrated hydrazine on the B-Z reaction are studied. Hydroxylamine sulfate and hydrated hydrazine can react with BrO to produce Br-. They show some analogies with vitamin C in their effects on B-Z reaction, that is, they sbolarly lengthen the induction period and oscillating period,and shorten the life-span of this oscillating reaction.From this reason the conjecture of reaction mechanism that is proposed by Zhao Xuezhuang et al can be confirmed.
出处 《物理化学学报》 SCIE CAS CSCD 北大核心 1994年第5期449-451,共3页 Acta Physico-Chimica Sinica
关键词 硫酸羟胺 水合肼 B-Z反应 Hydroxylamine sulfate, Hydrated hydrazine, B-Z reaction
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参考文献4

  • 1李京,物理化学学报,1989年,5卷,44页
  • 2赵学庄,科学通报,1985年,10卷,586页
  • 3张义学,物理化学学报,1985年,1卷,350页
  • 4陈寿椿,重要无机化学反应(第2版),1982年

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