摘要
利用变温穆斯堡尔谱研究了铋系高T_c氧化物超导体在正常态上及正常态-超导态转变过程中晶格振动的性质。穆斯堡尔谱无反冲因子的测量结果表明,在超导转变温度以上的120K和200K附近的两个温区上,分别出现了明显的铜-氧层晶格软化效应。这种晶格振动的异常行为,是超导转变的前驱效应。同质异能移位和无反冲因子得到德拜温Θ_D为310-350K。测量同质异能移位、四极劈裂和谱线线宽也观察到超导转变前晶格的反常变化行为和d电子的离域效应。
The dynamic studys of the lattice vibrational behaviors and hyperfine interacti-ons on the Bi-based high-T_c superconductors are conducted by means of Mossbauermeasurement.The recoilless fractors show that there is a significant lattice softeni-ng on Cu-O layers,above superconducting temperature,around 126 and 260K respe-ctively.Such anomalous behavior is thought to be a precursor effect of supercondu-ctivity. The recoilless fractors and the isomer shifts show that the Debye tempera-ture Θ_D=310-350K。 Based on the measurement of isomer shift,quatrupole spli-ting and spectroscopy width. it can be seen that both softening of lattice vibrationalmodes and delocalization effect on d-electron orbits exsist.
出处
《物理学报》
SCIE
EI
CAS
CSCD
北大核心
1994年第3期465-475,共11页
Acta Physica Sinica
基金
国家超导技术联合研究开发中心资助课题