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纳米氧化锌压敏陶瓷 被引量:5

Fabrication of Nanometer ZnO Varistors
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摘要 采用多元掺杂法以纳米级的ZnO为原料制备纳米ZnO压敏陶瓷,通过SEM,TEM,XRD等现代分析方法对其组织结构进行表征,并测量其压敏性能。实验结果表明,压敏陶瓷的粉体平均粒径可达到30nm;压敏电压Vb=462V;漏电流IL=1.2μA;非线性系数α可达到45;而且随着烧结温度的升高,晶粒尺寸逐渐增大,结构逐渐均匀、致密。 In this article , nanometer ZnO varistor ceramic is fabricated by means of several additives together, and through SEM, TEM, XRD, etc. high-tech methods,the structure and properties of nanopowder ZnO varistors are studied. The experimental results indicate that the general grain size of nanopowder is about 30nm, V_b= 462 V, I_L=1.2 μA, α=45. With the increasing in sintering temperature, the grain grows up gradually, there is uniformity and densification in the microstructure.
出处 《太原理工大学学报》 CAS 北大核心 2005年第2期115-118,共4页 Journal of Taiyuan University of Technology
基金 国家自然科学基金资助项目(50471070) 教育部博士点基金资助项目(20041023)
关键词 ZNO 压敏陶瓷 电性能 微观结构 ZnO varistors electric properties microstructure
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参考文献5

  • 1Sung G Y, Kim C H. Anisotropic grain growth of ZnO grain in the varistor system ZnO-Bi2O3-MnO2-TiO2 [J]. Adv Ceram Mater, 1988,3 (6): 604-606.
  • 2Suzki H,Bradt R C. Grain growth of ZnO in ZnO-Bi2O3 ceramics with TiO2 additional[J]. J Am Ceram Soc, 1995, 78 (5):1 354-1 360.
  • 3Mendelson M L. Average grain size in polycrystalline ceramics[J]. J Am Ceram Soc,1969,52(8):443-446.
  • 4Suzuki H, Bradt R C. Grain growth of ZnO in ZnO-Bi2O3 ceramics with TiO2 additives[J]. J Am Ceram Soc, 1995,78(6) :1 354-1 360.
  • 5Nunes S I, Bradt R C. Grain growth during liquid-phase sintering of ZnO -Bi2O3 ceramics with Nb2O3 additions[J]. J Am Ceram Soc, 1995,78 (5) :1 361-1 371.

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