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Study on the reaction activity of CuO/γ-Al_2O_3 for dry flue gas desulfurization

Study on the reaction activity of CuO/γ-Al_2O_3 for dry flue gas desulfurization
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摘要 The copper oxide bed regenerable adsorber process can efficiently remove sulfur dioxide (SO2) and sulfur trioxide (SO3) and reduce nitrogen oxides (NOX) from flue gas with no solid or liquid byproducts. This paper investigates the dry flue gas desulfu- rization activities of the CuO/γ-Al2O3 under different operation conditions finding that the dispersion degree of copper oxide can achieve a threshold value, which is 0.47 mg/m2 carriers. The conclusion confirms that the sulfur capacity of desulfurizer is asso- ciated with flue gas’ space velocity, reaction temperature, copper content and the struc- ture of sorbent pellet, etc. And with the condition of the desulfurization reaction tem- perature 673 K, the space velocity 11 200 h-1 and the S/Cu mole ratio under 1, the sulfur removal efficiency can go upwards to 95%. The copper oxide bed regenerable adsorber process can efficiently remove sulfur dioxide (SO2) and sulfur trioxide (SO3) and reduce nitrogen oxides (NOX) from flue gas with no solid or liquid byproducts. This paper investigates the dry flue gas desulfu- rization activities of the CuO/γ-Al2O3 under different operation conditions finding that the dispersion degree of copper oxide can achieve a threshold value, which is 0.47 mg/m2 carriers. The conclusion confirms that the sulfur capacity of desulfurizer is asso- ciated with flue gas’ space velocity, reaction temperature, copper content and the struc- ture of sorbent pellet, etc. And with the condition of the desulfurization reaction tem- perature 673 K, the space velocity 11 200 h-1 and the S/Cu mole ratio under 1, the sulfur removal efficiency can go upwards to 95%.
出处 《Journal of Coal Science & Engineering(China)》 2004年第2期80-84,共5页 煤炭学报(英文版)
基金 Supported by the Special Fund for Major State Basic Research Project (G1999022207)
关键词 flue gas DESULFURIZATION copper oxide CuO/γ-Al2O3 SO3 SO2
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