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冷冻处理对日本柳杉边材炭化的影响(英文) 被引量:6

Effect of Pretreatment with Freezhing on Carbonization of Sugi (Cryptomeria japonica) Sapwood
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摘要 将冷冻处理前后的日本柳杉边材在 4 0 0℃下进行炭化 ,得到了木醋液、木焦油和木炭。与没有处理相比 ,虽然处理过边材的木焦油的收率几乎不变 ,木醋液的收率显示增加倾向 ,但是木炭的收率有减少迹象。用毛细管气相色谱法对得到的木醋液中的 11种成分进行了定量分析。与无处理相比较后 ,发现处理过边材木醋液中的甲醇、脂肪酸及糠醛 (呋喃甲醛 )的收量有了变化 ,但是 5 -羟甲基糠醛、麦芽酚、苯酚、邻苯二酚及愈创苯酚的收量几乎没有变化。 Sugi sapwoods at different moisture content after and before freezing treatment were carbonized at 400 ℃ to afford wood-vinegar, wood-tar and charcoal. Yield of wood-vinegar prepared from the treated wood tended to increase, and yield of charcoal indicated opposite tendency, but yield of wood-tar was almost constant.11 components in wood-vinegar obtained from the Sugi sapwoods after and before treatment were determined by capillary gas chromatography (capillary GC). The change in amounts of methanol, carboxylic acids and 2-furaldehyde in wood-vinegar from the treated sapwood was observed, but amounts of 5-hydroxymethyl-2-furaldehyde, maltol, phenols, pyrocatechol, and guaiacols were almost constant.
出处 《林业科学》 EI CAS CSCD 北大核心 2005年第1期131-135,共5页 Scientia Silvae Sinicae
关键词 日本柳杉 木醋液 边材 冷冻处理 木炭 脂肪酸 成分 炭化 收率 呋喃甲醛 Sugi (Cryptomeria japonica) sapwood freezing treatment carbonization wood-vinegar capillary gas chromatography (capillary GC)
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  • 1Kabeya H. 1993. Effect of grinding on bound water in cellulosic materials. Mokuzai Gakkaishi, 39( 11 ): 1291 - 1297.
  • 2Kojima T, Ooi N. 1985. Kikibunseki System Gasukuromatogurafuhou. Japan, Kyouritusyutubann, 120- 121.
  • 3Matsui T, Matsushita y, Sugamoto K, et al. 2002. Analysis of wood-vinegars prepared from Sugi (Cryptomeriajaponica D. Don) sapwood and its components. Nippon Kagaku Gakkaishi, 3(3) : 385 - 392.
  • 4Matsui T, Matsushita y, Sugamoto K, et al. 2002. Influence of moisture content of Sugi ( Cryptomeriajaponica D. Don) wood on yields of carbonization products and constituents of wood-vinegar. Miyazakidaigaku Kougakubukenkyuukiyou, 31:69 - 74.
  • 5Murry R G, WⅡⅡam H C, George R G. 1985. Pyrolysis of a wood-derived material. Effect of moisture and ash content. Ind Eng Chem Des Dev, 24 : 646 - 651.

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