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同多钒酸盐[Zn(phen)_2]_2[V_4O_(12)]·3H_2O的水热合成及晶体结构 被引量：6

Hydrothermal Synthesis, Structure and Characterization of a Isopolyvanadate[Zn(phen)_2]_2[V_4O_(12)]·3H_2O
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摘要 利用水热合成方法合成了组成为[Zn(phen)2 ]2 [V4O12 ]·3H2O的化合物,它以V4O4-12 和Zn(phen)2+2 形成的六核簇为结构单元且通过氢键作用而形成超分子体系. 晶体结构数据如下:三斜晶系,空间群Pī,a= 1. 029(2)nm, b= 1. 111(2)nm, c= 1. 327(3)nm,α= 105. 36 ( 3 )°,β= 92. 01 ( 3 )°,γ= 108. 79 ( 3 )°, V=1. 372 ( 5 )nm3, Z= 1, Dcalc= 1. 575g·cm-3,F(000) = 2 577, R1 = 0. 078 0, wR2 = 0. 175 4. V_(4)O^(4-)_(12) and Zn(phen)^(2+)_(2) form \_(2)\ 3H_(2)O under hydrothermal condition in the presence of a heterometallic hexanuclear cluster, and there is hydrogen bonding resulting in a supermolecule. Crystal data as follows: triclinic, Pī, a = 1.029(2)nm, b = 1.111(2)nm, c = 1.327(3)nm,α = 105.36(3)°,β = 92.01(3)°,γ = 108.79(3)°, V =1.372(5)nm^(3), Z = 1, D_(calc)= 1.575 g·cm^(-3), F(000) = 2 577, R_(1)= 0.078 0, wR_(2)= 0.175 4.
作者 沈月 于丽 赵俊伟 王敬平
机构地区 河南大学化学化工学院
出处 《河南大学学报（自然科学版）》 CAS 北大核心 2005年第1期35-38,共4页 Journal of Henan University:Natural Science
基金 河南省杰出创新人才工程项目 河南省自然科学基金(0411051700)
关键词 水热合成 同多钒氧酸盐 六核簇 Hydrothermal synthesis Isopolyvanadate Hexanuclear
分类号 O612.5 [理学—无机化学]
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参考文献19

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同被引文献65

  • 1连照勋,黄长沧,张汉辉,黄细河,杨宏芳.(H_2en)_2[Se_2Mo_5O_(21)]2H_2O的水热合成、晶体结构与光谱研究[J].Chinese Journal of Structural Chemistry,2004,23(6):605-611. 被引量：3
  • 2李杰,刘迎红,马鹏涛,王敬平.二维层状钒氧化合物Co(bpy)(H_2O)V_2O_6的水热合成和晶体结构[J].河南大学学报（自然科学版）,2006,36(3):33-36. 被引量：3
  • 3王晓丹,马慧媛,李春香,武立州.三维钒氧化合物的水热合成与表征[J].分子科学学报,2007,23(1):55-57. 被引量：2
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河南大学学报（自然科学版）
2005年 第1期

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