三苯基锡(Ⅳ)N-烃基哌嗪氨荒酸酯配合物的合成、表征、性质和Ph_3SnS_2CN(C_2H_4)_2NCH_3的晶体结构

Synthesis, Characterization and Properties of Triphenyltin N-alkylpiperazinyldithiocarbamate and Crystal Structure of Ph_3SnS_2CN(C_2H_4)_2NCH_3

Six triphenyltin?髧 N-alkylpiperazinyldithiocarbamates have been synthesized by the reaction of triphenyltin chloride with N-alkylpiperazinyldithiocarbamates and characterized by elemental analysis, UV, IR and 1H NMR. The crystal structure of Ph3SnS2CN(C2H4)2NCH3 (1) has been determined by X-ray single crystal diffraction. The crystal of the compound 1 belongs to triclinic with space group P1, a=1.033 56(18) nm, b=1.148 8(2) nm, c=1.191 6(2) nm, α=66.282(2)°, β=78.756(2)°, γ=67.476(2)°, Z=2, V=1.195 2(4) nm3, Dc=1.460 g·cm-3, μ=1.256 mm-1, R=0.025 1, wR=0.058 3. The structure shows a distorted tigonal bipyramidal configuration with five-coordination for the central tin atom. CCDC: 240375.

Six triphenyltin(IV) N-alkylpiperazinyldlthiocarbamates have been synthesized by the reaction of triphenyltin chloride with N-alkylpiperazinyldithlocarbamates and characterized by elemental analysis, UV, IR and H-1 NMR. The crystal structure of Ph3SnS2CN(C2H4)(2)NCH3 (1) has been determined by X-ray single crystal diffraction. The crystal of the compound 1 belongs to triclinic with space group P-1, a=1.033 56(18) nm, b=1.148 8(2) nm, c=1.1916(2) nm, alpha=66.282(2)degrees, beta=78.756(2)degrees, gamma=67.476(2)degrees, Z=2, V=1.195 2(4) nm(3), D-c=1.460 g(.)cm(-1), mu=1.256 mm(-1), R=0.025 1, wR=0.058 3. The structure shows a distorted tigonal bipyramidal configuration with five-coordination for the central tin atom.