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新型线性β-环糊精高分子的合成与表征 被引量：2

Synthesis and Characterization of Novel Linear β-Cyclodextrin Containing Polymer
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摘要 β-环糊精(β-CD)经过单磺酰化和氨化后与丙烯酸在催化剂1,3-二环己基碳化二亚胺(DCC)的作用下,合成了分子中带有乙烯基的单取代丙烯酰乙二胺β-环糊精(β-CD-6-EA)。将β-CD-6-EA与两种功能性单体甲基丙烯酸-N,N-二甲氨基乙酯(DMA)和丙烯酸(AAc)在紫外光辐照下共聚,分别合成了两种新型线性环糊精高分子。 Mono-[6-(2-acryloylaminoethyl) amino]-6-(-CD (β-CD-6-EA) and acryloyl-(-CD both carrying vinyl groups which can be polymerized with other functional monomers were also synthesized.The results indicated β-CD-6-EA can be obtained by using dicyclohexylcarbodiimide (DCC) as condensation agent with a higher yield. Two linear (-cyclodextrin containing polymer,β-CD-6-EA-co-DMA and β-CD-6-EA-co-AAc, were synthesized by copolymerization of (-CD-6-EA with N,N-dimethylaminoethyl methacrylate (DMA) and acrylic acid (AAc) using a redox initiator system in aqueous solutions.
作者 黄怡 范晓东
机构地区 咸阳师范学院化学系 西北工业大学理学院应化系
出处 《咸阳师范学院学报》 2004年第6期19-24,共6页 Journal of Xianyang Normal University
基金 国家自然科学基金资助项目(编号:20374040)
关键词 Β-环糊精 线性高分子 甲基丙烯酸-N N-二甲氨基乙酯 丙烯酸 β-Cyclodextrin, Polymer, N,N-dimethylaminoethyl methacrylate, acrylic acid
分类号 O631.6 [理学—高分子化学]
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参考文献12

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共引文献17

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咸阳师范学院学报
2004年 第6期

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