ANBDF的合成和稳定性研究

Synthesis of 7-Amino-6-nitrobenzodifuroxan and its Thermal Properties

以3, 5 二硝基苯甲酸为原料,经氨化、硝化和叠氮化热解脱氮成环三步反应合成出了7 氨基6 硝基苯并二氧化呋咱(ANBDF)。ANBDF中含有氨基、硝基及苯并氧化呋咱环,这些基团与苯环处于同一平面,TGA和DSC分析均证明ANBDF是一热稳定性很高的高能炸药。

amino-6-nitrobenzodifuroxan (ANBDF) was synthesized through three reactions from starting material 3,5-dinitrobenzoic acid with high yield. ANBDF molecule contains one amino-group, one nitro-group and two benzofuroxan rings that are on the benzene ring and are on the same plane. This particular structure characterizes its high thermal stability. The results of TGA and DSC show that ANBDF is an excellent explosive with high thermal stability.