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渐消递推滤波辅助光谱分析最佳自适应算法

FADING RECURSIVE FILTERING AIDED SPECTROSCOPY An Optimal Adaptive Algorithm
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摘要 研究了Kalman渐消递推最佳滤波辅助光谱辨析。基于Kalman滤波达到最优时其新息序列互不相关的性质,提出了一种新的渐消滤波─—最佳自适应算法。通过在线自适应地调整遗忘因子从而使滤波(器)在存在模型误差或受到外扰时仍保持收敛性和最优性。用于重叠峰的辨识,能取得更好效果。 The fading Kalman recursive optimal filtering is studied for spectroscopicresolution,Based on the nature of Kalman filter that the residual sequenees arenot correlated when the optimal gain is obtained, a new fading filtering-optimaladaptive algorithm is proposed and utilized. Through the on-line and adaptiveadjustment of the fading or forgetting factor,the convergency and optimality ofKalman filtering are improved using measured outputs or estimated results, evenwhen there exist model errors and/or when the system is affected by unmeasurableexternal disturbances.The algorithm developed is applied to overlapped peakresolution with good results.
出处 《应用科学学报》 CAS CSCD 1994年第2期150-158,共9页 Journal of Applied Sciences
基金 国家开放实验室与自然科学基金及四达应用化学研究所基金
关键词 渐消递推滤波 自适应算法 光谱分析 fading recursive filtering,Kalman filter,optimal adaptive algorithm,chemometrics,spectroscopic resolution,multicompo- nent analysis.
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参考文献5

  • 1李志良,Anal Chim Acta,1991年,248卷,1期,257页
  • 2李志良,Chinese Journal of Chemistry,1990年,48卷,10期,1018页
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  • 4李志良,Chem J Chin Univ,1989年,10卷,6期,575页
  • 5李志良,1988年

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