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有机硅合成产物Y-PJ中残留Si-H的红外光谱定量分析 被引量:31

A Quantitative Analysis of the Remaining Si-H in Silicone polymer y-PJ by Means of IR Spectroscopy
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摘要 选择四甲基四氢环四硅氧烷作模型化合物,利用Si-H伸缩振动在216Ocm ̄(-1),的吸收作定量分析峰,以红外光谱法测定含氢硅油和烯丙基醚加成产物中残留Si-H的含量,所得结果与化学法测定结果一致。 In this paper a new way for the determination of Si-H groups content in the addition product of hy-drogen polysiloxane fluid and allyl-ether by means of IR was described,selecting tere-methyl tere-hydrogencyclosilicone as model compound and Si-H stretching vibration(2 1 60cm ̄(-1))as qualitative analysis absorp-tion bands.The results showed there was no difference with that of chemical analysis.
出处 《有机硅材料及应用》 1994年第5期12-13,7,共3页
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