摘要
利用新型泵式沸点仪,在 101. 3kPa下测定了乙烯基三氯硅烷—乙烯基三甲氧基硅烷二元体系汽液相平衡的数据,用间接法推算了与之平衡的气相组成,并用基团贡献法计算了乙烯基三甲氧基硅烷的临界参数和偏心因子,分别用Wilson、NRTL、Margules、VanLaar四种模型进行了关联,结果令人满意,拟合精度可以满足工程设计的要求.
Isobaric vapor-liquid equilibrium data of vinyltrichlorosilane + vinyltrimethoxysilane binary system was determined at 101.3kPa with a new type of magnetical pump-ebulliometer. At the same time, the saturated vapor pressure of vinyltrimethoxysilane was measured. The experimental data was correlated with the Wilson, NRTL, Margules and Van Laar equations and the results were satisfactory.
出处
《南昌大学学报（工科版）》
CAS
2005年第1期46-48,共3页
Journal of Nanchang University(Engineering & Technology)
基金
江西省自然科学基金资助项目(0020019)
