9,10-二(2-亚甲基-硫-亚甲基-6-氯吡啶)蒽的合成及其对Ag^+的识别

Synthesis of 9,10-Bis(2- Methylene -Sulfur-Methylene -6-Chlorpyridine) Anthracene and Its Recognition with Ag^+

以蒽为原料经过一系列反应合成了荧光分子 9, 10 二 ( 2 亚甲基 硫 亚甲基 6 氯吡啶 )蒽,其结构经IR,1HNMR所证实.利用紫外光谱法考察了该化合物对Ag+,Zn2+的识别性能.结果表明,该化合物对Ag+具有良好的识别能力.从主客体的大小形状匹配及配位识别原子等方面对受体的识别能力进行了讨论.

In this thesis the 9,10-bis(6-methylene sulfur-2-chlorpyridine)anthracene derived from the starting material anthracene is synthesized and characterized by IR,~1HNMR.The result of molecular recognition test shows that this host molecular has strong complexation to Ag^+. The mechanism of recognition is discussed by us.