不同尺寸ZnS:Mn纳米粒子的静压光致发光研究

INVESTIGATION OF PHTOLUMINESECENCE UNDER HYDROSTATIC PRESSURE IN DIFFERENT SIZED ZnS:Mn NANOPARTICLES

测量了ZnS:Mn纳米粒子以及相应体材料在不同压力下的光致发光谱.随压力增大,来源于Mn2+离子的4T1 6A1 跃迁的桔黄色发光明显红移.体材料和 10, 4. 5, 3. 5, 3nm的ZnS:Mn纳米粒子中Mn2+发光的压力系数分别是-29. 4±0. 3和-30. 1±0. 3, -33. 3±0. 6, -34. 6±0. 8, -39±1meV/GPa,压力系数的绝对值随粒子尺寸减小而增大,该种尺寸关系由晶体场场强Dq和Racah参数B值的尺寸依赖性引起. 1nm样品的Mn2+发光的特殊压力行为是因为样品的粒子尺寸比较小,另外,分布在Y型沸石中的纳米粒子的表面状况也不同于其它样品.

The PL spectra for the 10, 4. 5, 3. 5, 3, 1 nm sized ZnS:Mn(2+) nanoparticles and corresponding bulk material under different pressures were investigated. The orange emission band originated from the (4)T(1)-(6)A(1) transition of Mn(2+) ions showed obvious red shift with the increasing of pressures. The pressure coefficients of Mn-related emissions measured from bulk, 10, 4. 5, 3.5 and 3 nm samples are -29.4 +/- 0.3, -30.1 +/- 0.3, -33.3 +/- 0.6, -34.6 +/- 0.8 and -39 +/- 1 meV/GPa, respectively. The absolute value of the pressure coefficient increases with the decrease of the size of particles. The size dependence of crystal field strength Dq and Racah parameter B accounts for the size behavior of the Mn-related emission in ZnS:Mn nanoparticles. The pressure behavior of Mn-related emission in the 1 nm sized sample is somewhat different from that of other nanoparticles. It may be due to smaller size of 1 nm sample and the special surface condition since ZnS nanoparticles are formed in the cavities of ziolite-Y for the 1 nm sample.