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二阶标准加入法误差传递的Monte Carlo模拟 被引量：1

ERROR ANALYSIS OF SECOND-ORDER STANDARD ADDITION METHOD BY MONTE CARROL SIMULATION
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摘要 介绍二阶标准加入法的应用步骤 ,讨论影响分析结果准确度的各种因素。以一个模拟的两组分激发 -发射荧光数据体系为例 ,采用MonteCarlo技术 ,模拟二阶标准加入法应用过程中标准加入次数、加入量、移液误差及测量误差对分析结果准确度的影响。所得结论可在实验设计及操作中作为参考。 Steps of the second-order standard addition method are introduced. Factors influencing the accuracy of results were discussed. A typical data set of two constituents obtained by using excitation-emission fluorescence spectrometry is first simulated. Effects of four factors such as the number of standard addition, quantity of standard addition, errors of volume and measurement on the accuracy of results in second-order standard addition method are principally discussed by Monte Carrol simulation. Some results are obtained which could be regarded as reference in experimental design.
作者 龙宁 吴海龙
机构地区 广东药学院 湖南大学
出处 《化学分析计量》 CAS 2004年第5期18-21,共4页 Chemical Analysis And Meterage
关键词 标准加入法 CARLO模拟 误差传递 二阶 分析结果 数据体系 应用过程 测量误差 实验设计 准确度 加入量 荧光 second-order standard addition method, Monte Carrol simulation, propagation of error
分类号 O657.31 [理学—分析化学] O631.1 [理学—高分子化学]
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参考文献6

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  • 2张大康.随机误差传递与合成的蒙特卡罗模拟[J].岩矿测试,1994,13(2):154-158. 被引量：3
  • 3许苏清,陈立奇.利用卫星数据估算南大洋海-气CO_2通量的展望[J].极地研究,2007,19(2):151-157. 被引量：6
  • 4宋清.定量分析中的误差和数据评价[M].北京:高等教育出版社,1982.
  • 5Are Olsen,Joaquin A. Triuanes, Rik Wanninkhof. Se>air flux of COz in the Caribbean Sea estimated using in situ and remote sensing data [J] Remote Sensing of Environment, 2004,89 ; 309 - 325.
  • 6Brent G T Else, John J Yackel, Tim N Papakyriakou. Application of satellite remote sensing techniques for estimating ai sea CO2 fluxes in Hudson Bay, Canada during the ice-free season [J]. Remote Sensing of Environment, 2008, 112 :3550-3562.
  • 7Chen Liqi, Xu Suqing, Gao Zhongyong, et al. Estimation of monthly ai sea CO2 flux in the southern AtLantic and Indian Ocean using in situ and remotely sensed data[J]. Remote Sensing of Environment, 2011,115 ; 1935- 1941.
  • 8Padin X A, Navarro G, Gilcoto M, et al. Estimation of ai sea CO2 fluxes in the Bay of Biscay based on empirical relationships and remotely sensed observations[J]. Journal of Marine Systems,2009, 75 : 280- 289.
  • 9Colin Sweeney. The annual cycle of surface water CO2 and 02 in the Ross Sea : A model for gas exchange on the continental shelves of Antarctica [J]. Biogeochemistry of the Ross Sea, 2003,78 :295 312.
  • 10Zhai Weidong, Dai Minhan. On the seasonal variation of ai>sea CO2 fluxes in the outer ChanRiiang (Yangtze River) Estuary, East China Sea[J]. Marine Chemistry, 2009, 117 : 2- 10.

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化学分析计量
2004年 第5期

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