一个新的噻二唑衍生物H_2ADTZ与锰的二维聚合物的合成与晶体结构(英文) 被引量：7

Synthesis, Crystal Structure and Properties of a New Thiadiazolen Two-dimensional Polymer of H2ADTZ with Mn(Ⅱ)

下载PDF

导出

摘要 A new 1,3,4 thiadiazole-derivative ligand 2,5-(s-acetic acid) dimercapto-1,3,4 thiadiazole (H2ADTZ) and its one-dimensional manganese polymer Mn(ADTZ)·4H2O had been synthesized and structurally characterized by X-ray single crystal diffraction in this paper. The Mn(Ⅱ) ion is coordinated with a distorted octahedron by two oxygen atoms from neighboring two deprotonated ligands ADTZ2- and other four oxygen atoms from four coordinated water molecules. The structural feature of the title compound is the formation of one-dimensional manganese chains polymer through the bridging of dioxygen O-O units. In the solid state structure of the complex, one-dimensional manganese chains are joined together by the weak intermolecular hydrogen bonds and vander Waals interactions forming a two-dimensional supramolecular compound. Furthermore, the UV spectra and electro-chemical properties of the title compound were also investigated. CCDC: 260532. A new 1,3,4 thiadiazole-derivative ligand 2,5-(s-acetic acid) dimercapto-1,3,4 thiadiazole (H2ADTZ) and its one-dimensional manganese polymer Mn(ADTZ)·4H2O had been synthesized and structurally characterized by X-ray single crystal diffraction in this paper. The Mn(Ⅱ) ion is coordinated with a distorted octahedron by two oxygen atoms from neighboring two deprotonated ligands ADTZ2- and other four oxygen atoms from four coordinated water molecules. The structural feature of the title compound is the formation of one-dimensional manganese chains polymer through the bridging of dioxygen O-O units. In the solid state structure of the complex, one-dimensional manganese chains are joined together by the weak intermolecular hydrogen bonds and vander Waals interactions forming a two-dimensional supramolecular compound. Furthermore, the UV spectra and electro-chemical properties of the title compound were also investigated. CCDC: 260532.

作者娄新华朱玉高辉朱爱新樊耀亭侯红卫卢会杰

机构地区郑州大学化学系

出处《无机化学学报》 SCIE CAS CSCD 北大核心 2005年第5期716-720,共5页 Chinese Journal of Inorganic Chemistry

基金国家自然科学基金资助项目(No.20471053) 国家重点基础研究专项基金资助项目(No.2003CB214500) 郑州大学能源工程资助项目。

关键词二维聚合物晶体结构衍生物噻二唑 TOGETHER CRYSTAL complex SPECTRA 合成 vander Mn(Ⅱ) solid with The 锰 new its ion are is Mn(Ⅱ) polymer thiadiazole-derivative hydrogen bonds cyclic voltammetry

分类号 TP311.5 [自动化与计算机技术—计算机软件与理论] V259 [一般工业技术—材料科学与工程]

引文网络
相关文献

参考文献3

1卢会杰,高洁,杜晨霞,樊耀亭,侯红卫,丁德刚,翟俊玲.钴的二苯甲酰甲烷配合物:晶体结构及其轴向置换反应(英文)[J].无机化学学报,2003,19(2):174-178. 被引量：1
2杜晨霞,薛东旭,程小宁,樊耀亭,侯红卫,卢会杰.一个新的钴磷酸盐配合物Co(μ_3-O_3P)·H_2O的合成与晶体结构[J].无机化学学报,2004,20(8):955-958. 被引量：2
3聂国朝.三乙胺催化合成2,5-二巯基-1,3,4-噻二唑[J].精细化工中间体,2003,33(5):32-34. 被引量：2

二级参考文献30

1高永建,张治军,薛群基.噻二唑及其衍生物的制备[J].化学研究,1997,8(3):60-62. 被引量：18
2曹泽环,孙岩,谈明传,孙涛,贺俊.2,5-二巯基-1,3,4-噻二唑的合成[J].精细石油化工,1996,13(4):31-33. 被引量：10
3郭奇珍陈馨娥.2，5-二琉基-1，3，4-噻-唑及其衍生物的制备[J].化学学报,1963,29(1):62-62.
4Ellis Fields. Addition of 1,3,4-thiadiazole-2,5-dithiol to Olefinic Compounds[J]. J Org Chem., 1956,21:497.
5Bhattacharya A, Singh T, Verma V K,etc. 1,3,4-Thiadiaoles as potential Ep additive-a tribological evaluation using a four-ball test[J]. Tribol Int, 1995,28(3):189-194.
6Ren T H,XUE Q J, W H Q. A study of S-(1H-bensotriazol-yl)methyl N, N-dialkyldithiocarbanmates as novel multifunctional oladditives[J]. Wear, 1994,172(1) :59-64.
7Jan Sandstrom. Cyclisations of Thiocarbohydraside and its Monohydrazones, Part Ⅲ : Reactions with Catrhon disulphide in Pyridine[J ]. Acta Chem Scand, 1961,15 : 1295 - 1302.
8Daxi Wang, Li Shuymm, Ying Yu,etc. Theoretical and Experimental Studies of Structure and Inhibition Efficiency of Inidazoline Derivatives[ J ]. Corrosion Science, 1999,41 ( 10 ) : 19111919.
9Max Busch. Ueber eine neue Reaction Zwischen Schwefelkohlenstoff und Primaren Hydrazine [ J ]. Bet. 1894, 27 ( 2 ) :2507-2521.
10Wilson S. T., Lok B. M., Messina C. A., Cannan T. R.,Flanigen E. M. J. Chem. Soc., Chem. Commun., 1982,104,1146.

共引文献2

1高辉,朱伯仲,廖洛,吴朝军,樊耀亭.钴的二膦酸配合物[Co(en)_3][Co_2(Hedbbp)_2]·7H_2O的合成与晶体结构[J].化学研究,2006,17(1):1-4. 被引量：1
2张奇龙,朱兴城,朱必学.新型含席夫碱大环化合物的合成[J].有机化学,2008,28(7):1254-1258. 被引量：5

同被引文献61

1邹小毛,程永浩,任雪玲,胡方中,杨华铮.新型吡唑腙类化合物的合成[J].有机化学,2005,25(5):554-557. 被引量：14
2杨新玲,陈馥衡.新型含噻二唑环磺酰脲的合成及其生物活性的研究[J].高等学校化学学报,1995,16(2):234-236. 被引量：12
3陈凤英,曹文凯,何水样,王保怀,张有民.RE(III)与2-羰基丙酸水杨酰腙配合物的合成、表征及热化学[J].物理化学学报,2006,22(3):280-285. 被引量：7
4LU J Y, RUNNEL K A. An unprecedented mixed-valent-copper mutual-face-insertion layered metal-organic polymer diaplaying graphite-like properties[J].Inorganic Chemistry Communications, 2001,4 : 678-681.
5CHOU J Y, LAI S Y, Pan S Let al. Investigation of anticancer mechanism of thiadiazole-based compound in human non-small cell lung cancer A549 cells[J]. Biochemical Pharmacology, 2003,66 : 115 -124.
6PALASKA E,SAHIN G, KELICEN P, et al. Synthesia and anti-inflammatory activity of 1-acylthiosemicarbazides, 1,3, 4-oxadiazoles, 1,3,4-thiadiazoles and 1,2,4-thiazole-3-Thiones[J]. Ⅱ Facrmaeo, 2002,57 :101-107.
7JOSHI S D,VAGDEVI H M,VAIDYA V P, et al. Synthesis of new 4-pyrrol-1-yl benzoic acid hydrazide analogs and some derived oxadiazole,triazole and pyrrole ring systems:Anovel class of potential antibacterial and antituhercular agents [J]. Europen Journal of Medicinal Chemistry, 2008,43,1989-1996.
8JOHNS B A,WEATHERHEAD J G,ALLEN SH,et al. 1,3,4-Oxadiazole substituted naphthyridines as HIV-1 integrase inhibitors Part 2 : SAR of the C5 position [J]. Bioorganie & Medicinal Chemistry Letters, 2009,19 ; 1807-1810.
9CHEN C J,SONG B A,YANG S,et al. Synthesia and antlfungal aetivitiesof 5-(3,4,5-Trime-thoxyphenyl)-2-sulfonyl-1,3,4-thiadiazole and5-(3,4, 5-trimethoxyphenyl)-2-sulfonyl-1,3,4-oxadiazole derivatives [J]. Bioorganie & Medicinal Chemistry, 2007, 15 : 3981-3989.
10Biing-Chiau Tzeng,Ya-Ling Wu.A novel trinuclear Re(Ⅰ) complex containing 1,3,4-thia-diazole-2,5-dithiolate:structural and spectroscopic properties.New J.Chem.,2007,31:199-201.