摘要
本文在８５～１７０℃、常压及高纯风气氛下，采用微型积分反应器研究了活性氧化里催化剂上羰基硫水解反应本征动力争实验数据以改进的Ｍａｒｑｕａｒｄｔ法进行搜索、选优，确定了ＣＯＳ和Ｈ２Ｏ的反应级数分别为１和０；并提出了符合水解反应规律的Ｒｉｄｅａｌ－Ｅｌｅｙ机理模型。
The intrinsic kinetic model of hydrolysis of carbenyl sulfide over actiivated alumina cata-lyst was investigated using a miniature integral flow reactor,under atmospheric pressure and temperature range 85-170℃。Modified non-linear Marquardt method was used to get optimum values for calculations,The established kinetic model is as follows:Zero-order and first-order behavior were observed for H2O and COS,respectively.A Rideal-Eley surface reaction mechanism was put forward which seemed most compatible with the experimental data
