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琥珀酸-氨基葡糖-二价铜络合物清除超氧阴离子自由基的研究

Studies on scavenged effect of O_2 by amberacid chitosan complex with copper (II)
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摘要 By use of steady photo-irradiation in the system of riboflavin aqueous solution containing methyl-sulf-amino acid and superoxide dismutase (SOD) as competitive scavenger of O2, the rate constant of superoxide anion radi- cal(O2 ·)scavenged by (Amberacid-chitosan-complex with copper (II), ACCC) was determined as 1.26×109, ? 1.11×109 and 4.98×108 mol-1 s-1 dm3 under irradiation of 254nm, 365nm UV lights and sun light, respectively. The results also show that the scavenge rate of O2 · by ACCC reached 91%, which is about the same as with ? natural SOD (93%), and is far more higher than the O2 · scavenge rate with just amberacid or chitosan, which is ? only 2.6% and 5.8%, respectively. By use of steady photo-irradiation in the system of riboflavin aqueous solution containing methyl-sulf-amino acid and superoxide dismutase (SOD) as competitive scavenger of O2, the rate constant of superoxide anion radi- cal(O2 ·)scavenged by (Amberacid-chitosan-complex with copper (II), ACCC) was determined as 1.26×109, ? 1.11×109 and 4.98×108 mol-1 s-1 dm3 under irradiation of 254nm, 365nm UV lights and sun light, respectively. The results also show that the scavenge rate of O2 · by ACCC reached 91%, which is about the same as with ? natural SOD (93%), and is far more higher than the O2 · scavenge rate with just amberacid or chitosan, which is ? only 2.6% and 5.8%, respectively.
作者 马建华
出处 《辐射研究与辐射工艺学报》 CAS CSCD 北大核心 2005年第2期72-72,共1页 Journal of Radiation Research and Radiation Processing
基金 国家自然科学基金(30100035)资助
关键词 琥珀酸-氨基葡糖-二价铜络合物 超氧阴离子自由基 清除效应 速率常数 Amberacid-chitosan- complex with copper (II), Superoxide anion radical, Scavenging effect, Rate constant
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参考文献3

  • 1Shi S Q, LIU Z X, LID X. J Applie Chem, 1998, 15(2): 52-54.
  • 2Butje K, Nakamoto K. Inorg Ghem Acta, 1990, 167(1): 97-101.
  • 3HU X, GUANG L Y. Biosci Biotechnol Biochem, 1998, 62(2): 206-209.

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