若干金属簇（配）合物的质谱和碎片重组反应研究

Mass Spectroscopic Studies and Recombination Reactions of Fragment Species of Some Metal Complexes and Clusters

质谱是结构化学研究工具，又是一种化学反应器，因此，它既可用于解释分子结构及其能量相关性，又可提供气相离子化学反应进行化学合成的一种有效手段，本文结合这两方面研究结果加以总结。

The mass spectrometry is both a tool for structural determination and a reactor ochemical synthesis in gas phase. Thus it offerds both informations of molecular structures and gas phase molecular-ion reactions. This paper summarizes the results on hot]topics: (1)comparison of EI and FAB mass spectrometry and its correlation to clusteconversion for MoFe3S4L5 (L= S2CNC4H8) cuban-type clusters F (2) the recombinatiolreaction of fragment species of some metal complexes and clusters in mass spectrometry.