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锂离子二次电池新型正极材料LiMPO_4(M=Fe、Co、Ni等)的研究进展 被引量：1

Progress on new-type cathode materials LiMPO_4(M=Fe, Co, Ni and Mn)for lithium-ion rechargeable batteries
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摘要 综述了锂离子二次电池新型正极材料LiMPO4(M=Fe、Co、Ni、Mn等)的研究进展。重点对该材料的结构、结构与电化学性能的关系、多种阳离子掺杂对材料性能的影响以及多种合成方法进行了较详细的评述,并对该材料的应用前景进行了展望。 The structures, the correlations between structure and electrochemical performance, the doping of multi-cations and the various synthesis methods of LiMPO_4(M=Fe, Co, Ni and Mn ) cathode materials for lithium-ion rechargeable batteries are reviewed and evaluated in detail. The application prospects of these cathode materials are forecast.
作者 孙玉恒 何泽珍 刘兴泉
机构地区 中国科学院研究生院 中国科学院成都有机化学研究所功能材料研究开发中心
出处 《化工科技》 CAS 2005年第2期49-56,共8页 Science & Technology in Chemical Industry
基金 四川省科技攻关重点项目 (0 2GG0 980 )资助课题 中国科学院青年创新基金 中国科学院"西部之光"人才计划后续资助项目。
关键词 锂离子 电池 正极材料 LiMPO4 橄榄石结构 化学性能 骨架材料 Lithium-ion batteries Cathode materials LiFePO_4 Olivine structure Progress
分类号 TM911.1 [电气工程—电力电子与电力传动]
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参考文献50

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同被引文献15

  • 1常晓燕,王志兴,李新海,匡琼,彭文杰,郭华军,张云河.锂离子电池正极材料LiMnPO_4的合成与性能[J].物理化学学报,2004,20(10):1249-1252. 被引量：15
  • 2张宝,常晓燕,王志兴,李新海,杨志,郭永兴,郭华军,彭文杰.4V级锂离子电池用橄榄石型LiMnPO_4的电化学性能[J].中南大学学报（自然科学版）,2005,36(6):960-964. 被引量：10
  • 3黄可龙,杨赛,刘素琴,王海波.磷酸铁锂在饱和硝酸锂溶液中的电极过程动力学[J].物理化学学报,2007,23(1):129-133. 被引量：6
  • 4Brown P J, Forsyth J B, Tasset F. Studies of Magneto-electric Crystals Using Spherical Neutron Polarimetry [J]. Solid State Sciences, 2005, 7(6): 682-689.
  • 5Cheng K. Evaluation of Crystallization Kinetics of Glasses by Nonisothermal Analysis [J], J. Mater. Sci., 2001, 36: 1043-1048.
  • 6Koga N, Tanaka H. Apparent Kinetic Behavior of Thermal Decomposition of Synthetic Malachite [J]. Thermochim. Acta, 1999, 340/341: 387-394.
  • 7Li G H, Azuma H, Tohda M. Optimized LiMnrFe1-yPO4 as the Cathode for Lithium Batteries [J]. J. Electrochem. Soc, 2002, 5(6): A135-A137.
  • 8Jun M, Qin Q z. Electrochemical Performance of Nanocrystalline LiMPO4 Thin-films Prepared by Electrostatic Spray Deposition [J]. J. Power Sources, 2005, 148(1): 66-71.
  • 9Drezen T, Kwon N H, Bowen P, et al . Effect of Particle Size on LiMnPO4 Cathodes [J]. J. Power Sources, 2007, 174(2): 949-953.
  • 10Yang J, Xu J. Synthesis and Characterization of Carbon-coated Lithium Transition Metal Phosphates LiMPO4 (M=Fe, Mn, Co, Ni) Prepared via a Nonaqueous Sol-Gel Route [J]. J Electrochem. Sot., 2006. 153(4): A716-A723.

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化工科技
2005年 第2期

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