自蔓延高温合成V_3TiNi_(0.56)Al_(0.2)贮氢材料

Materials Hydrogen Storage V_3TiNi_(0.56) Al_(0.2) by Self-propagating High-temperature synthesis

通过对反应体系的绝热温度计算及热力学分析,讨论了V2O5 -TiO2 -Al体系自蔓延反应进行的可行性。自蔓延高温合成了V3TiNi0. 56Al0. 2贮氢合金,利用X射线衍射分析(XRD)、能谱分析、扫描电镜(SEM)和金相显微镜等手段对产物进行了研究。结果表明,用自蔓延高温合成法与用其他方法制备的V3TiNi0. 56Al0. 2贮氢合金的相结构一样。PCT曲线表明该合金具有一定的吸放氢性能,饱和吸氢量为0. 092L/g,略低于其它方法制备的V3TiNi0. 56Al0. 2的饱和吸氢容量。

With the help of the calculation of adiabatic temperature and thermodynamic analysis of the reactive system the autaurs discuss possibility about system of V 2O 5-TiO 2-Al by Self-propagating High-temperature synthesis(SHS).Hydrogen Storage V 3TiNi 0.56 Al 0.2 by SHS is studied by XRD,SEM and scanning electron microscopy.The experiment result indicates that it has same microstructure between synthesization by SHS and other ways.PCT curve indicated that alloy has certain hydrogen storage capability,saturated capacity of hydrogen storage is 0.092 L/g,which is a little lower than alloy by other ways.