固相配位化学反应研究——ⅩⅩⅧ MoS_4^(2-)的固相成簇反应

STUDIES ON SOLID STATE REACTIONS OF COORDINATION COMPOUNDS——ⅩⅩⅧ STUDIES ON SOLID STATE REACTIONS OF Mos_4^(2-) FOR PRODUCING CLUSTERS

本文研究了(NH_4)_2MoS_4和(n-Bu)_4NBr之间以及(Ph_4P)_2MoS_4自身的两个固相成簇反应。在不同温度、不同气氛反应条件下分别合成了[Ph_4P]_2[Mo_3O_2S_9]、[(n-Bu)_4N]_2[Mo_2O_2S_6]、[(n-Bu)_4N]_2[Mo_2OS_7]和[(n-Bu)_4N]_2[Mo_3S_9]。并进行了红外光谱,电子光谱、熔点和X—射线分析测定。

(?) we have studied the solid state reaction of (NH4)2MoS4 itself and reactions of (NH4) (?) with (n-Bu)4 NBr for producing clusters. Four compounds (Ph4P)2 (Mo -Bu)4N]2(Mo2OS5), [(n-Bu)4N]2(MO2OS7), and [(n-Bu)4]2(Mo3S9) were by controlling reaction conditions. The physical properties described and discussed in- clude spectra, electronic spectra and melting point.