S-(1-二茂铁烷基)硫代乙醇酸与胺的反应——一类新型二茂铁衍生物的合成与性质研究

REACTIONS OF S-(1-FERROCENYLALKYL) THIO-GLYCOLIC ACIDS WITH AMINES-STUDIES ON SYNTHESES AND PROPERTIES OF A NOVEL TYPE OF FERROCENYL DERIVATIVES

Ratajczak等研究了S-(1-二茂铁烷基)疏代乙醇酸的合成与反应(?)Ugi等将它们与羟胺反应,合成了一种有用的手性模板试剂。最近,Czech等用键合载体液相色谱对它们进行了光学拆分研究。本文报导了此类化合物与胺的反应,合成了一类新的化合物(?)二茂铁烷基)硫代乙醇酸胺。

This article reported reactions of S-(1-ferrocenylalkyl)thioglycolic acids and amines. Some novel type of ferrocenyl derivatives-alkyl ammonium S-(1-ferrocenylalkyl) thioglycolic were synthesized and characterized by elemental analyses.IR and H NMR spectroscopy. Their molar conductance ratios were measured, and some influences of kinds of amines were discussed.