摘要
本文对Ln(phen)(C_6H_5COO)_3、Ln(phen)_2P-(OC_6H_4CHO)_3·3H_2O.Ln(phen)_2P-(OC_6H_4COOC_2H_5)_3(Ln=Tb、Eu)固体配合物的制备和光谱性质进行了研究。根据元素分析、红外光谱、摩尔电导测定,X射线粉末衍射、热重差热分析以及紫外可见光谱确定了其组成及配位形式,并对其发光性能进行了研究。
In this paper, the synthesis and spectral properties of Tb(Eu) (phen)(C6H5COO)3, Tb(Eu)(phen)2(OC6H4CHO)3·3H2O, Tb(Eu)(phen)2(OC6H4COOC2H5)3 were reported. Their composition were confirmed by elementary analysis. Their solubility molar conductance,thermogravimetric analysis,differential thermal analysis were also determined.They were characterized by X-ray powder diffraction, infrared, UVand fluoreccnt spectra analysis.
出处
《无机化学学报》
SCIE
CAS
CSCD
北大核心
1989年第4期84-87,共4页
Chinese Journal of Inorganic Chemistry
关键词
稀土配合物
邻啡罗啉
芳香化合物
rare earth 1,10-phenanthroline benzoic acid p-hydroxybenzaldehyde ethyl p-hydroxybenzoate ternary coordination compound
