垃圾焚烧飞灰中重金属的分布与性质

Distribution and Characters of Heavy Metals from Municipal Solid Waste Incinerator Fly Ash

以华东某城市为案例,研究我国城市生活垃圾焚烧飞灰中重金属污染物的分布和性质.结果表明,重金属污染物主要集中于小粒径飞灰中.连续提取实验表明Cd、Pb、Mg、Cu等重金属在环境中具有较强的迁移性,Ag和Sn相对比较稳定.重金属元素的溶出与酸度密切相关,与环境关系较大的Cd、Co、Cu、Mn、Ni、Pb和Zn等元素在酸性条件下表现出最强的溶出能力,但Cr和As则倾向于在碱性条件下溶出.

The distribution and characters of heavy metals from municipal solid waste incinerator fly ash was studied in East China. The result indicate that heavy metals in fly ash were mainly distributed in fine particles. The heavy metals including Cd, Pb, Mg, and Cu could migrate easily from fly ash while Ag and Sn would be more stable. The metal mobility changed with the pH level. For environmentally important metals such as Cd, Co, Cu, Mn, Ni, Pb, and Zn, the increase in mobility due to the decrease in pH was more pronounced and significant than for other elements, while Cr and As with the opposite condition.