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新型荧光增白剂的合成和表征 被引量：1

Synthesis and Characterization of a New Fluorescent Whitening Agent
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摘要 以4,4′-二(氯甲基)联苯、亚磷酸三乙酯、2,4-二氯苯甲醛为原料通过Arbuzow重排和Wittig-Horner缩合反应合成了新型荧光增白剂4,4′-双(2,4-二氯苯乙烯基)联苯.该化合物用IR、1H-NMR、13C-NMR、MS、元素分析等进行了结构表征.荧光分析表明其强度比常用的荧光增白剂VBL高4.5倍. The fluorescent whitening agent is synthesized by using 4,4′-bis(chloromethyl)biphenyl,triethylphosphate and 2,4-dichloro-benzaldehyde as starting materials through Arbuzow resetting and Wittig-Horner condensating reaction. The structure of the product is characterized by IR,1H-NMR, 13C-NMR,MS,EA. The fluorescence analysis shows its intensity is 4.5 times higher than that of VBL.
作者 胡建立 郭芳茹 李云霞
机构地区 郑州大学化学系
出处 《郑州大学学报（理学版）》 CAS 2005年第2期92-94,共3页 Journal of Zhengzhou University:Natural Science Edition
基金 河南省科委重点攻关项目 编号39870822.
关键词 荧光增白剂VBL 亚磷酸三乙酯 二氯苯甲醛 反应合成 苯乙烯基 ^13C 结构表征 元素分析 NMR 氯甲基 化合物 ^1H 强度比 分析表 联苯 缩合 重排 fluorescent whitening agent 2,4-dichloro-benzaldehyde 4,4′-bis(2,4-dichlorostyryl)biphenyl synthesis characterization
分类号 TQ265.1 [化学工程—有机化工] TS192.14 [轻工技术与工程—纺织化学与染整工程]
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共引文献26

同被引文献13

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引证文献1

郑州大学学报（理学版）
2005年 第2期

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