β－苯乙胺N－取代反应中的重排反应

A New Rearrangement in N-Substitution of β-Phenylethylamine

合成了Ｎ－（对硝基苯氧乙基）β－苯乙胺（３），同时分离到重排产物Ｎ－（２－苯乙基）－Ｎ－（２－羟乙基）－对硝基苯胺（４），推测可能是一分子内亲核取代反应。

N-(p-nitrophenoxyethyl)β-phenylethylamine(3)was synthesized.An rearrangement product N-(2-phenylethyl)-N-(2-hydroxyethyl)-P-nitro-phenylamine(4)was isolated from the reaction mixture.The mechanism was proposed as an intramolecular neucleophilic substitution.