大环配体过渡金属配合物 Ⅲ.四-(2-硫-苯甲酰硫基)-四氮杂卟啉及其过渡金属配合物的合成与光谱

TRANSITION METAL COORDINATION COMPOUNDS OF MACROCYCLIC LIGAND Ⅲ. Syntheses and Spectra of Tetra-(2-thio-benzoyl-mercapto)-tetraazaporphyrin and its Transition metal coordination compounds

以自制的1,2-二氰基-1′,2′-二苯甲酰硫乙烯为单体,用板模法合成了四-(2-硫-苯甲酰硫基)-四氮杂卟啉及其Mn(Ⅱ)、Fe(Ⅱ)、Co(Ⅱ)、Ni(Ⅱ)、Cu(Ⅱ)及Zn(Ⅱ)的配合物。研究了这7个新化合物的红外光谱、电子光谱等性质与结构的关系。

The tetra-(2-thio-benzoylmercapto)-tetraazaphorhyrin H_2T(tbm)TAP and its transition metal coordination compounds MT(tbm)TAP(M=Mn(Ⅱ), Fe(Ⅱ), Co(Ⅱ), Ni(Ⅱ), Cu(Ⅱ), and Zn(Ⅱ)) have been synthesized according to the template reaction method from prepared bis-(benzoylmereapto) maleonitrile. The infrared and electronic absorption spectra for the seven new compounds have been studied. The relationship between their properties and structure has been discussed.