摘要
The condensation product from D-glucose and N,N’-diamino-diphenyl-methan was prepared and the optimal synthetic conditions were determined;D -Glucose and N,N’-Diamino-diphenyl-methane(1mol∶1mol)were dissolved in anhydrous methanol,reflux raction 25h,yield 53.3%,purity 99.4%,and its structure was characterized by elemental analysis,IR and NMR spectroscopy.The hydrolysis of the condensation product was studied,and results show that the condensation reaction was at equilibrium,and the influence of time and the N,N’-diamino-dimphenyl-methan concentration in water on the hydrolysis were researched.
The condensation product from D-glucose and N,N'-diamino-diphenyl-methan was prepared and the optimal synthetic conditions were determined;D -Glucose and N,N'-Diamino-diphenyl-methane(1mol∶1mol)were dissolved in anhydrous methanol,reflux raction 25h,yield 53.3%,purity 99.4%,and its structure was characterized by elemental analysis,IR and NMR spectroscopy.The hydrolysis of the condensation product was studied,and results show that the condensation reaction was at equilibrium,and the influence of time and the N,N'-diamino-dimphenyl-methan concentration in water on the hydrolysis were researched.
出处
《化学研究与应用》
CAS
CSCD
北大核心
2005年第3期414-416,共3页
Chemical Research and Application
基金
国家自然科学基金资助项目(29972020)
