摘要
采用solgel法制备TiO2薄膜。以该薄膜为催化剂,研究了在H2O2存在的条件下,对内分泌干扰物质邻苯二甲酸乙酯(DEP)的光催化降解反应。分别讨论了pH值、H2O2的加入量、DEP的初始浓度以及光照时间对降解反应的影响。结果表明在pH=2、50mg/L的H2O2中对初始浓度为50mg/L的DEP溶液光照150min有较好的降解效果。
The photocatalytic degradation of diethyl phthalate (DEP). one of the Endocrine Disrupting Chemicals (EDO, was studied, with TiO2 thin film prepared by sol-gel method as photocatalyst and a 125W mercury lamp as ultraviolet light source. The influences of various parameters were studied. Results showed that the best photodegradation of DEP is under the condition of pH 2, 50mg/L H2O2 and 150min irradiation.
出处
《环境科学与技术》
CAS
CSCD
北大核心
2005年第4期39-41,共3页
Environmental Science & Technology
基金
湖北省教育厅2004年重点科研项目(2004x121)
湖北省建设厅2003年科技攻关项目(k200308)
关键词
TIO2薄膜
光催化
邻苯二甲酸乙酯
TiO_2 thin film
photocatalytic degradation
diethyl phthalate