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含聚氧化乙烯侧链的聚合物凝胶电解质的动态力学性能和离子导电性 被引量:2

Dynamic Mechanics and Ion Conductivity of Cmblike Polymer Gel Electrolytes
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摘要 红外测试结果表明产物是含聚氧化乙烯侧链的聚合物。该聚合物电解质的室温电导率为10-3S/cm数量级。并用动态力学方法,研究了分子链段活动性与聚合物凝胶电解质组成(增塑剂含量、含盐量和盐种类)的关系。 A comblike gel polymer electrolyte was synthesized. IR spectroscopic measurements indicated that the structure of the comblike polymer was in accord with what we designed. The conductivity of the comblike polymer electrolyte prepared at room temperature is at magnitude range of 10^-3 S·cm^-1 . The relation between the molecular segment movement and the composition (i.e. the content of plasticizer, the content of salt and kinds of salts) of comblike polymer gel electrolytes was studied by the dynamic mechanical method. Polymer gel electrolytes with good mechanical properties were obtained.
作者 齐力 董绍俊
出处 《功能高分子学报》 CAS CSCD 北大核心 2005年第2期232-238,共7页 Journal of Functional Polymers
关键词 聚合物电解质 锂聚合物电池 电导率 动态力学性能 丙烯腈 聚氧化乙烯 polymer electrolyte lithium polymer battery conductivity dynamic mechanical properties, acrylonitrile, poly(ethylene oxide)
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